Photodissociation of methylacetylene at 193 nm
Journal Article
·
· Journal of Physical Chemistry
- Howard Univ., Washington, DC (United States)
FTIR spectroscopy was used to study the photolysis of methylacetylene at 193 nm to yield CH{sub 3}C{sub 2}+H and CH{sub 2}+C{sub 2}H{sub 2}. CD{sub 3}C{sub 2}H photolysis confirmed that acetylene-d{sub 1} is a primary product. Photolysis of CD{sub 3}C{sub 2}H and Cl{sub 2} mixtures produce HCl only, indicating that H atoms are immediately dissociated from the triple-bonded carbon. 21 refs., 9 figs., 2 tabs.
- Sponsoring Organization:
- USDOE
- OSTI ID:
- 437077
- Journal Information:
- Journal of Physical Chemistry, Journal Name: Journal of Physical Chemistry Journal Issue: 8 Vol. 96; ISSN JPCHAX; ISSN 0022-3654
- Country of Publication:
- United States
- Language:
- English
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