Study of thermally activated radical pair separation in the anthraquinone/triethylamine photoredox system by fourier transform EPR
Journal Article
·
· Journal of Physical Chemistry
- Univ. of Leipzig (Germany)
- Univ. of Dortmund, Otto-Hahn-Strasse (Germany)
By using fourier tranform electron paramagnetic resonance, the free radicals in the photoreduction of anthraquinone by triethylamine in alcohol solutions have been investigated. The detrapping kinetics have been described using some analytical form of the potential and the thermally averaged distance distribution of trapped radical pairs. This analytical form relates the binding potential, the diffusion constant, and the equilibrium distance. 12 refs., 4 figs., 3 tabs.
- Sponsoring Organization:
- USDOE
- OSTI ID:
- 437052
- Journal Information:
- Journal of Physical Chemistry, Journal Name: Journal of Physical Chemistry Journal Issue: 8 Vol. 96; ISSN JPCHAX; ISSN 0022-3654
- Country of Publication:
- United States
- Language:
- English
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