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Optical properties of multicomponent cadmium-silver nanocluster composites formed in silica by sequential ion implantation

Conference ·
OSTI ID:436386
 [1]; ;  [2]
  1. Oak Ridge National Lab., TN (United States)
  2. Vanderbilt Univ., Nashville, TN (United States). Dept. of Applied and Engineering Sciences

Formation and optical properties of nanometer dimension metal colloid composites formed by sequential implantation of Cd then Ag and by single element implantations of Cd and Ag in silica were characterized by TEM and optical spectroscopy. A nominal dose of 6x10{sup 16} ions/cm{sup 2} as determined by current integration was used for both ion species. Doses used for the sequential implantations were a 1 to 1 ratio of Cd to Ag. Sequential implantations of Cd and Ag led to formation of both multi-component metal nanoclusters and elemental nanoclusters. Electron diffraction indicated that the polycrystalline particles of Ag{sub 5}Cd{sub 8} and elemental Ag were formed. The optical response was consistent with results expected from effective medium theory.

Research Organization:
Oak Ridge National Lab., TN (United States)
Sponsoring Organization:
USDOE Office of Energy Research, Washington, DC (United States); Department of Defense, Washington, DC (United States)
DOE Contract Number:
AC05-96OR22464
OSTI ID:
436386
Report Number(s):
CONF-961202--16; ON: DE97001292; CNN: Grant DAAH04-93-G-0123; Grant DAAH04-94-G-0147
Country of Publication:
United States
Language:
English