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Rates and kinetic hydrogen isotope effects for the ionization of phenylnitromethane

Journal Article · · J. Chem. Soc., Chem. Commun., no. 1, pp. 17-18
DOI:https://doi.org/10.1039/c39740000017· OSTI ID:4349941
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The general-base catalyzed ionization of phenylnitromethane is subject to large primary kinetic hydrogen isotope effects; these effects, their activation parameters, and the Bronsted catalysis coefficient for the reaction are used to discuss possible transition-state structures. (auth)

Research Organization:
Univ. of Kent, Canterbury, Eng.
NSA Number:
NSA-29-018114
OSTI ID:
4349941
Journal Information:
J. Chem. Soc., Chem. Commun., no. 1, pp. 17-18, Journal Name: J. Chem. Soc., Chem. Commun., no. 1, pp. 17-18; ISSN JCCCA
Country of Publication:
United Kingdom
Language:
English

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Related Subjects

*DEUTERIUM-- ISOTOPE EFFECTS
ACTIVATION ENERGY
AROMATICS
BASES
CATALYSIS
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
DEUTERIUM COMPOUNDS
HYDROCARBONS
HYDROGEN
HYDROGEN COMPOUNDS
IONIZATION
MOLECULAR STRUCTURE
N40220* --Chemistry--Inorganic
Organic
& Physical Chemistry--Isotopic Effects
NITRO COMPOUNDS