THE KINETICS OF THE EXCHANGE OF CHLORINE BETWEEN HYDROGEN CHLORIDE AND ACETYL CHLORIDE IN THE VAPOR PHASE
Journal Article
·
· Journal of the American Chemical Society (U.S.)
A measurable exchange has been observed between hydrogen chloride and acetyl chloride in the vapor phase. The exchange reaction was investigated over a temperature range from 0 to 29.6 deg ; the concentration of acetyl chloride ranged from 0.0026 to 0.0106 M and of hydrogen chloride from 0.0031 to 0.0080 M. Over the range of conditions studied the rate of exchange can be represented by R plus or minus 0.17e/sup -1550/RT (HCl) (CH/sub 3/COCl) where the units of R are liter a mole/sup -1/ a sec/sup -1/. A more complicated rate expression cannot be excluded but is not called for by the data. (auth)
- Research Organization:
- Univ. of New Mexico, Albuquerque
- Sponsoring Organization:
- USDOE
- NSA Number:
- NSA-12-009673
- OSTI ID:
- 4345356
- Journal Information:
- Journal of the American Chemical Society (U.S.), Journal Name: Journal of the American Chemical Society (U.S.) Vol. Vol: 80; ISSN JACSA
- Country of Publication:
- Country unknown/Code not available
- Language:
- English
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