New cationic bis({eta}{sup 3}-allyl) ruthenium(IV) complexes from allylic C-H bond activation of alkenes
- Toyohashi Univ. of Technology (Japan); and others
exo,endo (2a) and endo, endo (2b) isomers of the new bis-allylic Ru(IV) cationic complex [CpRu({eta}{sup 3}-C{sub 3}H{sub 5}){sub 2}] OTf (2) formed when (allyl)Ru{sup IV} complex CpRuBr{sub 2}({eta}{sup 3}-C{sub 3}H{sub 5}) (1) was treated with silver trifluoromethane-sulfonate (silver triflate, AgOTf) followed by the reaction with propene at 1 atm. The results of analogous studies with 2-butene and 1,5-dimethyl-1,5-cyclooctadiene were presented.
- Sponsoring Organization:
- USDOE
- OSTI ID:
- 433552
- Journal Information:
- Organometallics, Journal Name: Organometallics Journal Issue: 7 Vol. 12; ISSN ORGND7; ISSN 0276-7333
- Country of Publication:
- United States
- Language:
- English
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