Kinetic isotope effects in the reaction of fluorine atoms with molecular hydrogen. I. H$sub 2$/D$sub 2$ kinetic isotope effect
Journal Article
·
· J. Chem. Phys., v. 59, no. 7, pp. 3612-3615
OSTI ID:4330632
The kinetic isotope effect in the reaction of fluorine atoms with H/sub 2/ and D/sub 2/ was measured as a function of reaction temperature in the essed as an Arrhenius type equation: k/sub F+H2/ K/sub F+D2/= (1.04 plus or minus 0.02) expSTA(370 plus or minus 10)/RT!. Experimental were carried out in a flow system with direct of reaction products. Fluorine atoms are produced by dissociating SF/sub 6/ or CF/sub 4/ in a microwave discharge. (auth)
- Research Organization:
- Isotope Department, The Weizmann Institute of Science, Rehovot, Israel
- NSA Number:
- NSA-29-020661
- OSTI ID:
- 4330632
- Journal Information:
- J. Chem. Phys., v. 59, no. 7, pp. 3612-3615, Journal Name: J. Chem. Phys., v. 59, no. 7, pp. 3612-3615; ISSN JCPSA
- Country of Publication:
- United States
- Language:
- English
Similar Records
Intramolecular kinetic isotope effect in the reaction of fluorine atoms with methane-d$sub 2$ (CH$sub 2$D$sub 2$)
Absolute rate coefficients for F + H2 and F + D2 at t = 295 K. Interim report
Temperature dependence of the intramolecular kinetic isotope effect in the reaction system Cl + HD
Journal Article
·
Mon Dec 31 23:00:00 EST 1973
· J. Chem. Phys., v. 60, no. 1, pp. 49-52
·
OSTI ID:4334039
Absolute rate coefficients for F + H2 and F + D2 at t = 295 K. Interim report
Technical Report
·
Thu May 01 00:00:00 EDT 1980
·
OSTI ID:6917533
Temperature dependence of the intramolecular kinetic isotope effect in the reaction system Cl + HD
Journal Article
·
Sat Sep 01 00:00:00 EDT 1973
· J. Chem. Phys., v. 59, no. 5, pp. 2415-2419
·
OSTI ID:4330588