The Validity of Onsager's Reciprocal Relations in Ternary Diffusion
Journal Article
·
· Journal of Physical Chemistry
The validity of Onsager's reciprocal relations in ternary diffusion was verified by transformation of the thermodynamic expressions into concentration gradient form while assuming no volume flow. A table containing several systems is presented, and the estimated error is assigned solely to uncertainties in diffusion coefficients based on concentration gradients; however, some error undoubtedly exists in the activity coefficients since they were estimated in the absence of experimental data.
- Research Organization:
- Univ. of California, Livermore
- Sponsoring Organization:
- USDOE
- NSA Number:
- NSA-12-012245
- OSTI ID:
- 4329340
- Journal Information:
- Journal of Physical Chemistry, Vol. 62, Issue 6; Other Information: Orig. Receipt Date: 31-DEC-58; ISSN 0022-3654
- Country of Publication:
- Country unknown/Code not available
- Language:
- English
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