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U.S. Department of Energy
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SEPARATION OF URANIUM FROM ZIRCONIUM AND NIOBIUM BY SOLVENT EXTRACTION

Patent ·
OSTI ID:4323950

A process for separation of the uranium from zirconium and/or niobium values contained in 3 to 7M aqueous nitric acid solutions is described. This is accomplished by adding phosphoric acid anions to the nitric acid solution containing the uranium, zirconium, and/or niobium in an amount sufficient to make the solution 0.05 to 0.2M in phosphate ion and contacting the solution with an organic water-immiscible solvent such as MEK, whereby the uranyl values are taken up by the extract phase while the zirconium and niobium preferentially remain in the aqueous raffinate.

Research Organization:
Originating Research Org. not identified
NSA Number:
NSA-12-014398
Assignee:
U.S. Atomic Energy Commission
Patent Number(s):
US 2833616
OSTI ID:
4323950
Country of Publication:
United States
Language:
English