EQUILIBRIUM DISTRIBUTION OF DEUTERIUM IN THE CASE OF HYDROGEN EXCHANGE WITH LIQUID HYDROGEN CHLORIDE (in Russian)
The alpha value for isotopic equilibrium between hydrogen chloride and the aromatic C-H bond was secured; the obtained value was compared with alpha for the cases of the 0-H bond and the aliphatic C-H bond. Experiments for isotopic exchange in hydrocarbons were made with a chloride aluminum catalysis. In addition to experimental determination of the alpha value for the water system (liquid) and hydrogen chloride (gas), these values were calculated using spectral data; considering the corrections for iaharmonious oscillations in H/sub 2/0, HDO, HCl, and DCl molecules and the corrections for the ratio of vapor elasticity of H/sub 2/0 and HDO. The resulting values alpha /sub 0/ = 2.79, alpha /sub 25/ = 2.45, and alpha /sub 40/. coincide with tabulated experimental data. (R.V.J.)
- Research Organization:
- Karpov Inst. of Physical Chemistry
- NSA Number:
- NSA-13-003611
- OSTI ID:
- 4307839
- Journal Information:
- Doklady Akad. Nauk S.S.S.R., Journal Name: Doklady Akad. Nauk S.S.S.R. Vol. Vol: 122
- Country of Publication:
- Country unknown/Code not available
- Language:
- Russian
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