Organic Compounds of Zirconium. V. Studies of Zirconium Mandelates
Journal Article
·
· Journal of the American Chemical Society
The reaction of zirconyl chloride with mandelic acid in aqueous solution yields mainly zirconium monomandelate which dissolves in one equivalent of alkali. The tetramandelate is formed only in the presence of higher concentrations of hydrochloric acid. The reaction between zirconium isopropoxide and mandelic acid in benzene shows that the carboxyl group is more reactive than the hydroxyl group in replacing isopropyl alcohol; the latter becomes active only when a sufficient concentration of carboxyl groups is not available. The following; new compounds of zirconium have been isolated: Zr(C8H6O3)-(OPr-iso)2, Zr(C8H6O3)(C8H7O3) (OPr-iso), Zr(C8H7O3)2 and Zr(C8H6O3) (C8H7O3 )(OBu).
- Research Organization:
- Univ. of Lucknow, India
- Sponsoring Organization:
- USDOE
- NSA Number:
- NSA-12-015337
- OSTI ID:
- 4305522
- Journal Information:
- Journal of the American Chemical Society, Vol. 80, Issue 14; Other Information: Orig. Receipt Date: 31-DEC-58; ISSN 0002-7863
- Publisher:
- American Chemical Society (ACS)
- Country of Publication:
- Country unknown/Code not available
- Language:
- English
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Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
ALCOHOLS
ALKOXIDES
ALKYL RADICALS
BENZENE
BUTYL RADICALS
CHEMICAL REACTIONS
CONCENTRATION
HYDROCHLORIC ACID
HYDROXIDES
ISOMERS
ISOPROPYL RADICALS
MANDELIC ACID
ORGANIC ACIDS
ORGANIC COMPOUNDS
OXIDES
PHENYL RADICALS
PROPANOL
PROPYL RADICALS
QUALITATIVE ANALYSIS
QUANTITY RATIO
SOLUTIONS
WATER
ZIRCONIUM CHLORIDES
ZIRCONIUM COMPOUNDS
ZIRCONIUM OXIDES
ZIRCONYL COMPOUNDS
ALCOHOLS
ALKOXIDES
ALKYL RADICALS
BENZENE
BUTYL RADICALS
CHEMICAL REACTIONS
CONCENTRATION
HYDROCHLORIC ACID
HYDROXIDES
ISOMERS
ISOPROPYL RADICALS
MANDELIC ACID
ORGANIC ACIDS
ORGANIC COMPOUNDS
OXIDES
PHENYL RADICALS
PROPANOL
PROPYL RADICALS
QUALITATIVE ANALYSIS
QUANTITY RATIO
SOLUTIONS
WATER
ZIRCONIUM CHLORIDES
ZIRCONIUM COMPOUNDS
ZIRCONIUM OXIDES
ZIRCONYL COMPOUNDS