Intramolecular nucleophilic acyl substitution reactions mediated by samarium(II) iodide: A convergent approach to the preparation of enantiomerically enriched 4-hydroxy ketones from 3-iodopropyl carboxylates
Journal Article
·
· Journal of Organic Chemistry
- Univ. of Colorado, Boulder, CO (United States)
A combination of samarium(II) iodide and iron(III) catalyst have been investigated with respect to the ability to stereochemically convert carboxylates to ketones. Racemization of centers {alpha} to the carbonyl were observed.
- Sponsoring Organization:
- USDOE
- OSTI ID:
- 430427
- Journal Information:
- Journal of Organic Chemistry, Vol. 59, Issue 12; Other Information: PBD: 17 Jun 1994
- Country of Publication:
- United States
- Language:
- English
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