Aggregation of some of the Amine Extractant Species in Benzene
Journal Article
·
· Journal of Physical Chemistry
In light scattering measurements of 546 m mu the normal sulfates of tri- n-octylamine, di-1-isobutyl-3,5dimethylhexylamine, methyldi-n-octylamine, 1,3ethylpentyl-4-ethyloctylamine, and di-n-decylamine showed aggregation numbers of 1,4,9,11, and 38, respectively, in benzene solution. Tri-n-octylamine bisulfate is dimeric. The linear dependences on concentration of the 90*/0 deg scattering ratios indicated that these plexes of these amine sulfates were all monomeric a dimer. The monomeric natures of tri-n-octylamine sulfate and of the di-n-decylamine sulfate-uranyl sulfate complex were confirmed by isopiestic and viscosimetric measurements.
- Research Organization:
- Oak Ridge National Lab., Tenn.
- Sponsoring Organization:
- USDOE
- NSA Number:
- NSA-12-016954
- OSTI ID:
- 4303983
- Journal Information:
- Journal of Physical Chemistry, Journal Name: Journal of Physical Chemistry Journal Issue: 9 Vol. 62; ISSN 0022-3654
- Country of Publication:
- Country unknown/Code not available
- Language:
- English
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