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Effects of carboxylic acids on the rheological properties of crumb rubber modified asphalt

Journal Article · · Preprints of Papers, American Chemical Society, Division of Fuel Chemistry
OSTI ID:430338
;  [1]
  1. Western Research Institute, Laramie, WY (United States)

The Federal mandate of 1991-1995 on the use of scrap tires in Federal roadway construction sparked a major interest in gaining a fundamental understanding of the behavior of rubber in asphalt. This study is a systematic elucidation of what chemistry controls the final crumb rubber modified asphalt (CRMA) product quality. We discovered that the type and total acid content in the asphalt are the most influential chemical factors that determine the changes in the important roadway properties of shear modulus (G*) and loss angle ({delta}) of CRMA. Low acid (<0.005 m/L) asphalts were modified with three types of carboxylic acid and each made into CRMA using typical field mixing conditions of 1 hour at 175{degrees}C. Rheological measurements were then made at various storage times up to 192 hours following storage at both 156 and 200{degrees}C. We found the changes in CRMA theological properties correspond to the acid type spiked into the asphalt.

OSTI ID:
430338
Report Number(s):
CONF-960807--; CNN: Contract DTFH61-92C-00170
Journal Information:
Preprints of Papers, American Chemical Society, Division of Fuel Chemistry, Journal Name: Preprints of Papers, American Chemical Society, Division of Fuel Chemistry Journal Issue: 4 Vol. 41; ISSN ACFPAI; ISSN 0569-3772
Country of Publication:
United States
Language:
English

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