POLYMERIC GASEOUS MOLECULES IN THE VAPORIZATION OF ALKALI HALIDES
Journal Article
·
· Journal of Chemical Physics (U.S.)
The molecular species of alkali halide vapors in equilibrium with their respective condensed phases have been deduced by a mass spectroinetric analysis of the ions produced hy electron impact. Dimers, trimers, and in some instances tetramers M/sub n/ X/sub n/ were observed, with the lithium halides exhibiting more dimeric than monomeric species. The results are in substantial agreement with earlier molecular beam velocity selector experiments, and discordant with some recent infrared spectral studies. Some oddities in the ionization efficiency curves are also discussed. (auth)
- Research Organization:
- Argonne National Lab., Lemont, Ill.
- Sponsoring Organization:
- USDOE
- NSA Number:
- NSA-13-000088
- OSTI ID:
- 4291687
- Journal Information:
- Journal of Chemical Physics (U.S.), Journal Name: Journal of Chemical Physics (U.S.) Vol. Vol: 29; ISSN JCPSA
- Country of Publication:
- Country unknown/Code not available
- Language:
- English
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