INFRARED SPECTRA OF URANYL NITRATE HYDRATES AND RUBIDIUM URANYL NITRATE

Journal Article · Sat Nov 01 04:00:00 EST 1958 · Journal of the Chemical Society (England) Divided into J. Chem. Soc. A, J. Chem. Soc. B, etc.

DOI:https://doi.org/10.1039/jr9580003965· OSTI ID:4280797

Gatehouse, B M; Comyns, A E

The infrared spectra of uranyl nitrate di-, tri-, and hexahydrate have been examined from 3700 to 700 cm/sup -1/, with nitrogen of normal isotopic composition and enriched in N/sup 15/, and most of the bands are assigned. The spectrum of uranyl nitrate hexahydrate is in most respects that of a typical ionic nitrate. The spectra of uranyl nitrate di- and trihydrate are similar to the spectrum of rubldium uranyl nitrate, and all three are closely related to the fluorescence spectrum of cesium uranyl nitrate, studied by Dieke and Duncan. These spectra are all characteristlc of compounds having coordinated nitrato- groups, and structures are suggested for the molecules in crystals of the di- and the trihydrate which account for the observed splitting of many of the bands. (auth)

• Research Organization: University Coll., London; Atomic Energy Research Establishment, Harwell, Berks, Eng.
• NSA Number: NSA-13-004871
• OSTI ID: 4280797
• Journal Information: Journal of the Chemical Society (England) Divided into J. Chem. Soc. A, J. Chem. Soc. B, etc., Journal Name: Journal of the Chemical Society (England) Divided into J. Chem. Soc. A, J. Chem. Soc. B, etc. Vol. Vol: 3965-71; ISSN JCSOA
• Country of Publication: Country unknown/Code not available
• Language: English

Related Subjects

ANGULAR DISTRIBUTION
CESIUM NITRATES
CONFIGURATION
CROSS SECTIONS
CRYSTALS
DEUTERIUM
DEUTERON BEAMS
ENERGY LEVELS
ENERGY RANGE
ENRICHMENT
ERRORS
HYDROGEN COMPOUNDS
INFRARED RADIATION
IONS
LATTICES
MEASURED VALUES
MEV RANGE
MOLECULES
NITROGEN 15
NITROGEN COMPOUNDS
NUCLEAR EMULSIONS
NUCLEAR REACTIONS
PHYSICS AND MATHEMATICS
PROTONS
RUBIDIUM NITRATES
SPECTRA
TRITIUM
URANYL NITRATES