New phosphanyl-substituted titanium and zirconium alkoxide precursors for sol-gel processing
Conference
·
OSTI ID:427713
- Technischen Univ. Wien (Austria). Inst. fuer Anorganische Chemie
Zirconium and titanium alkoxide derivatives with phosphanyl substituents were synthesized by reaction of the alkoxides with 2-acrylamido-2-methyl-propane sulfonic acid followed by addition of HPPh{sub 2} to the acrylic double bond. Alternatively, the phosphinated sulfonic acid was prepared first and then reacted with the alkoxides. The second route is preferred because of the milder reaction conditions, shorter reaction times and avoidance of byproducts. The bifunctional organic ligand is bonded to the titanium or zirconium atom via the sulfonate group, while the PR{sub 2} group is available for further reactions such as the coordination of metal compounds.
- OSTI ID:
- 427713
- Report Number(s):
- CONF-960401-; ISBN 1-55899-338-X; TRN: IM9708%%39
- Resource Relation:
- Conference: Spring meeting of the Materials Research Society (MRS), San Francisco, CA (United States), 8-12 Apr 1996; Other Information: PBD: 1996; Related Information: Is Part Of Better ceramics through chemistry 7: Organic/inorganic hybrid materials; Coltrain, B.K. [ed.] [Eastman Kodak Co., Rochester, NY (United States)]; Sanchez, C. [ed.] [Univ. Pierre et Marie Curie, Paris (France)]; Schaefer, D.W. [ed.] [Sandia National Labs., Albuquerque, NM (United States)]; Wilkes, G.L. [ed.] [Virginia Polytechnic Inst. and State Univ., Blacksburg, VA (United States)]; PB: 695 p.; Materials Research Society symposium proceedings, Volume 435
- Country of Publication:
- United States
- Language:
- English
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