THE SEPARATION TUBE. XXII. EFFECT OF THE MASS DISTRIBUTION IN THE THERMAL DIFFUSION BETWEEN Ar$sup 40$ AND HCl$sup 35$, HCl$sup 37$, DCl$sup 35$, AND DCl$sup 3$$sup 7$

Journal Article · Wed Jan 01 04:00:00 EST 1958 · Helvetica Chimica Acta (Switzerland)

DOI:https://doi.org/10.1002/hlca.19580410743· OSTI ID:4276619

Clusius, K; Flubacher, P

The thermal diffusion alpha of Ar/sup 40/ in HCl/sup 35/, HCl/sup 37, DCl/sup 35/, and DCl/sup 37/ was measured at a temperature of 107 deg C. The ce HCl/sup 35/, HCl/sup 37/, and DCl/ sup 37/, instead of increasing with molecular weight. The simple mixture law is valid in the transition from H to D compounds, as it is in the transition from Cl/sup 35/, to Cl/sup 37/ compounds, but with a different factor. Apparently the effect is connected with the effect of the rotational quanta. The system of curves for the alpha value has the typical appearance of curves for the simultaneous effect of mass and diameter. (J.S.R)

• Research Organization: Univ. of Zurich
• Sponsoring Organization: USDOE
• NSA Number: NSA-13-007527
• OSTI ID: 4276619
• Journal Information: Helvetica Chimica Acta (Switzerland), Journal Name: Helvetica Chimica Acta (Switzerland) Vol. Vol: 41; ISSN HCACA
• Country of Publication: Country unknown/Code not available
• Language: German

Related Subjects

ARGON 40
CHEMISTRY
CHLORINE 35
CHLORINE 37
DEUTERIUM COMPOUNDS
DIAGRAMS
HYDROCHLORIC ACID
MASS
MEASURED VALUES
QUANTITY RATIO
QUANTUM MECHANICS
SEPARATION PROCESSES
THERMAL DIFFUSION
TUBES