Cleavage of N-O bonds promoted by samarium diiodide: Reduction of free or N-acylated O-alkylhydroxylamines
Journal Article
·
· Journal of Organic Chemistry
- CSIC, Madrid (Spain)
The authors examined the ability of samarium diiodide to promote N-O cleavage in N-acylated O-alkylhydroxylamines. The reaction offers a chemoselective and high-yield route to the preparation of corresponding amines or amides. 12 refs., 1 tab.
- OSTI ID:
- 426269
- Journal Information:
- Journal of Organic Chemistry, Journal Name: Journal of Organic Chemistry Journal Issue: 1 Vol. 61; ISSN 0022-3263; ISSN JOCEAH
- Country of Publication:
- United States
- Language:
- English
Similar Records
Intramolecular reductive coupling reactions promoted by samarium diiodide
Samarium diiodide-promoted reductive cleavage of carbon-sulfur bonds: A novel stereoselective generation of functionalized vinylsamarium species and synthesis of {beta}-thiobutenolides
Facile reductive cleavage of the C=O bond of acyl halides and the C identical with N bond of nitriles by hydrogen in the presence of sulfido-bridged molybdenum complexes
Journal Article
·
Wed Oct 11 00:00:00 EDT 1989
· Journal of the American Chemical Society; (USA)
·
OSTI ID:6947870
Samarium diiodide-promoted reductive cleavage of carbon-sulfur bonds: A novel stereoselective generation of functionalized vinylsamarium species and synthesis of {beta}-thiobutenolides
Journal Article
·
Thu Nov 18 23:00:00 EST 1993
· Journal of Organic Chemistry
·
OSTI ID:405342
Facile reductive cleavage of the C=O bond of acyl halides and the C identical with N bond of nitriles by hydrogen in the presence of sulfido-bridged molybdenum complexes
Journal Article
·
Tue Jan 06 23:00:00 EST 1987
· J. Am. Chem. Soc.; (United States)
·
OSTI ID:6874388