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NITROGEN ISOTOPIC FRACTIONATION BETWEEN NITRIC ACID AND THE OXIDES OF NITROGEN

Journal Article · · Journal of Chemical Physics (U.S.)
DOI:https://doi.org/10.1063/1.1730157· OSTI ID:4249143

The single-stage nitrogen isotopic separation factor between nitric acid and the oxides of nitrogen has been measured as a function of temperature and nitric acid concentration. Nitric acid molarities were varied from 1.084 to 15.45 and temperatures from 26 to 70 C were used. The separation factor was found to vary from 1.01 to 1.064, with nitrogen-15 concentrating in the nitric acid phase. The experimental data are compared with values calculated from spectroscopic and chemical data. (auth)

Research Organization:
Oak Ridge National Lab., Tenn.
Sponsoring Organization:
USDOE
NSA Number:
NSA-13-014938
OSTI ID:
4249143
Journal Information:
Journal of Chemical Physics (U.S.), Journal Name: Journal of Chemical Physics (U.S.) Vol. Vol: 30; ISSN JCPSA
Country of Publication:
Country unknown/Code not available
Language:
English

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