STRUCTURE OF THE REACTION PRODUCT OF PHENYLACETYLENE WITH IRON PENTACARBONYL
Journal Article
·
· Journal of the American Chemical Society (U.S.)
A compound first prepared by Jones, Wailes, and Whiting in 1955 has been further studied. It is concluded from analytical data that its formula is C/sub 20/H/sub 12/ O/sub 4/Fe and not C/sub 20/H/sub 10/O/sub 4/Fe. Detailed study of the infrared spectrum and the fact that it has a dipole moment of ~3 Debye units lead to the proposal of a structure in which a diphenylcyclopentadienone is bonded by pi electrons to an Fe(CO)/sub 3/ group. (auth)
- Research Organization:
- Massachusetts Inst. of Tech., Cambridge
- Sponsoring Organization:
- USDOE
- NSA Number:
- NSA-13-017879
- OSTI ID:
- 4241804
- Journal Information:
- Journal of the American Chemical Society (U.S.), Journal Name: Journal of the American Chemical Society (U.S.) Vol. Vol: 81; ISSN JACSA
- Country of Publication:
- Country unknown/Code not available
- Language:
- English
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