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U.S. Department of Energy
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PHYSICAL AND CHEMICAL PROPERTIES OF NUCLEAR POWER REACTOR WASTE SOLUTIONS

Journal Article · · Industrial and Engineering Chemistry (U.S.) Formerly J. Ind. Eng. Chem. Superseded by Chem. Technol.
OSTI ID:4235701
Approximate waste concentrations presented are typical of waste produced by Purex, TBP-25, STR, Darex, and SIR processes with fuels of current design. Evaporation of acidic waste provides the maximum reduction in volume to be secured by a simple treatment. Controlled heating of the dry residues further reduces the mass of the solid residue. Neutralization of the acidic wastes produces solid precipitates (ferric, aluminum, or zirconium hydroxide) which settle slowly and are difficult to filter; calcium hydroxide gave precipitates which filter more readily than sodium hydroxide-neutralized material. A flocculating agent improves settling rates, more for the calcium hydroxide neutralized material than for the sodium hydroxideneutralized. If neutralization is desirable before evaporation, the neutralized waste can be satisfactorily evaporated in a system which prevents bumping. (auth)
Research Organization:
Office of Civil Defense Mobilization, Battle Creek, Mich.; Oak Ridge NAtional Lab., Tenn.
NSA Number:
NSA-13-021651
OSTI ID:
4235701
Journal Information:
Industrial and Engineering Chemistry (U.S.) Formerly J. Ind. Eng. Chem. Superseded by Chem. Technol., Journal Name: Industrial and Engineering Chemistry (U.S.) Formerly J. Ind. Eng. Chem. Superseded by Chem. Technol. Vol. Vol: 51, No. 10; ISSN IECHA
Country of Publication:
Country unknown/Code not available
Language:
English