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Modified Sargent-Malmstadt Automatic Titrator for Remote Control Use with Plutonium Solutions

Journal Article · · Analytical Chemistry
DOI:https://doi.org/10.1021/ac60151a020· OSTI ID:4234730

Several modifications a adapt the commercially available, differential- potentiometric automatic titrator for use with plutonium solutions and to improve pads of it for specific purposes include replacing the gravityflow buret with a motor-driven syringe buret, replacing the stirrer with a magnetic stirrer, rewiring the titrator for remote operation inside a plutonium dry box or hood, and adding a microammeter to indicate potential changes. For trial titrations of cerium(IV) and chromium(IV) with iron(II), standard deviations of less than 0.01 relative % were obtained by using large samples and weight burets with the modified titrator.

Research Organization:
Los Alamos Scientific Lab., N. Mex.
Sponsoring Organization:
USDOE
NSA Number:
NSA-13-016165
OSTI ID:
4234730
Journal Information:
Analytical Chemistry, Journal Name: Analytical Chemistry Journal Issue: 7 Vol. 31; ISSN 0003-2700
Publisher:
American Chemical Society (ACS)
Country of Publication:
Country unknown/Code not available
Language:
English

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