Heavy metal speciation and uptake in crayfish and tadpoles
- Tulane Univ., New Orleans, LA (United States)
Developing valid pollution recording methods is central to assessing environmental damage and remediation. This often is difficult, however, because of speciation and multiphase distribution of contaminants. Polarography, an electroanalytical technique capable of detection and quantification of trace levels of elements and ionic complexes, is a promising method for analyzing environmental samples. Here, polarography has been used to determine lead concentration in water, sediment, bullfrogs, tadpoles, and adsorbed onto kaolin. It has also been used to measure hexavalent chromium concentration in crayfish. This research involves field studies and two laboratory experiments. Studies of a Louisiana swamp have shown lead`s affinity for sediment and water particulate phases, rather than being ionically dissolved in the aqueous phase. In swamp bullfrogs, lead was found in greater concentrations in bone compared to muscle. In the first laboratory experiment, lead uptake originating from water and sediment increased in tadpoles as exposure time and concentration increased. Also, this animal`s development was hindered at higher concentrations. The second laboratory experiment exposed crayfish to aqueous hexavalent chromium. Total chromium uptake increased with exposure time and concentration. The chromium tissue abundance was hepatopancreas > gills > muscle. A substantial portion of tissue hexavalent chromium converted to the less toxic trivalent form.
- Sponsoring Organization:
- USDOE, Washington, DC (United States)
- DOE Contract Number:
- FG21-93EW53023
- OSTI ID:
- 422819
- Report Number(s):
- CONF-9605266-; TRN: IM9707%%126
- Resource Relation:
- Conference: 9. Annual conference on hazardous waste remediation, Bozeman, MT (United States), 8-10 Jun 1994; Other Information: PBD: 1996; Related Information: Is Part Of Proceedings of the 1996 Hazardous Substance Research Center/Waste-management Education and Research Consortium joint conference on the environment; Erickson, L.E. [ed.] [Kansas State Univ., Manhattan, KS (United States)]; Grant, S.C. [ed.] [Haskell Indian Nations Univ., Lawrence, KS (United States)]; Tillison, D.L.; McDonald, J.P. [eds.]; PB: 706 p.
- Country of Publication:
- United States
- Language:
- English
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