THERMAL STABILITY AND TITRIMETRIC DETERMINATION OF DECABORANE

Journal Article · Fri Jan 01 04:00:00 EST 1960 · Analytical Chemistry (U.S.) Formerly Ind. Eng. Chem., Anal. Ed.

DOI:https://doi.org/10.1021/ac60157a026· OSTI ID:4217133

Fauth, M I; McNerney, C F

ABS>A method for the quantitative determination of decaborane consists of oxidation with pctassium icdate, reaction of excess iodate with potassium iodide, and titration of the liberated iodine with scdium thiosulfate. Acetic acid was found to be the most satisfactory solvent for the decaborane. Recoveries on the order of 98% have been obtained. Differential thermal analysis curves are presented for decaborane heated in air and in helium for the temperature range 20 deg to 150 deg C. (auth)

• Research Organization: U.S. Naval Propellant Plant, Indian Head, Md.
• Sponsoring Organization: USDOE
• NSA Number: NSA-14-005192
• OSTI ID: 4217133
• Journal Information: Analytical Chemistry (U.S.) Formerly Ind. Eng. Chem., Anal. Ed., Journal Name: Analytical Chemistry (U.S.) Formerly Ind. Eng. Chem., Anal. Ed. Vol. Vol: 32; ISSN ANCHA
• Country of Publication: Country unknown/Code not available
• Language: English

Related Subjects

ACETIC ACID
AIR
BORON COMPOUNDS
BORON HYDRIDES
CHEMISTRY
HEATING
HELIUM
IODATES
IODINE
MEASURED VALUES
OXIDATION
POTASSIUM COMPOUNDS
QUANTITATIVE ANALYSIS
RECOVERY
SOLVENTS
STABILITY
TEMPERATURE