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Title: Diffusion of Aluminum, Magnesium, Silicon, and Zirconium in Nickel

Journal Article · · Journal of Applied Physics
DOI:https://doi.org/10.1063/1.1735346· OSTI ID:4212914

The diffusion rates of aluminum, magnesium, silicon, and zirconium, alloyed as single additives in nickel, were measured at temperatures between 800 and 970 deg C. The method consisted of measuring the weight gain caused by surface oxidation of the additive in a wet hydrogen ambient. The surface oxides were identified by electron diffraction. Grain size was about 0.05 mm in Al-Ni, Si-Ni, and Mg-Ni but less than 10/sup -3/ mm in Zr-Ni. The composite volume and grain boundary diffusion coefficients are given by D/sub Al yields Ni/= 1.1 exp(- 59,500/RT); D/sub mg yields Ni/= 2.3 x 10/sup -5/ exp(-31,300/RT); D/sub zi yields /= 10.6 exp(-64,800/RT); D/sub Zr yields Ni/ = 1 x 10/sup -5/ exp(-26,700/ RT). Stereo and photomicrographs indicate considerable grain boundary diffusion, particularly in Mg-Ni and Zr-Ni.

Research Organization:
Bell Telephone Labs., Murray Hill, N.J.
Sponsoring Organization:
USDOE
NSA Number:
NSA-13-022470
OSTI ID:
4212914
Journal Information:
Journal of Applied Physics, Vol. 30, Issue 9; Other Information: Orig. Receipt Date: 31-DEC-59; ISSN 0021-8979
Publisher:
American Institute of Physics (AIP)
Country of Publication:
Country unknown/Code not available
Language:
English