Insertion of fluoroalkenes into activated C-H bonds for the preparation of polyfluorinated sulfanes, alcohols, and acyclic and cyclic ethers
- Univ. of Idaho, Moscow, ID (United States)
THe authors studied the chemical preparation of cyclic sulfanes with fluorinated side groups, fluorinated alcohols, and fluorinated ethers. The sulfane reactions proceed by free radical addition catalyzed by di-tert-butyl peroxide. Alcohols form as adducts of perfluoroallylbenzene. The alcohols can be converted to ethers under fairly mild conditions. X-ray crystal structures of a cyclic and an acyclic fluorinated ether were reported.
- OSTI ID:
- 420972
- Journal Information:
- Inorganic Chemistry, Journal Name: Inorganic Chemistry Journal Issue: 23 Vol. 35; ISSN 0020-1669; ISSN INOCAJ
- Country of Publication:
- United States
- Language:
- English
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