Studies on organolanthanide complexes. 53. Effect of rare earth metal radius on the molecular structure: Synthesis and X-ray crystl structure of bis((2-methyoxyethyl)cyclopentadienyl) rare earth metal chlorides
- Shanghai Institute of Organic Chemistry, Shanghai (China); and others
Chemical preparation and X-ray diffraction determined crystal structures of (CH{sub 3}OCH{sub 2}CH{sub 2}C{sub 5}H{sub 4}){sub 2}LnCl [Ln = La (1), Pr (2), Nd (3), Sm (4), Gd (5), Dy (6), Ho (7), Er (8), Tm (9), Yb (10), Lu (11), Y (12)] are reported. Further characterization by elemental analysis, MS, NMR, and IR spectroscopy was performed for these complexes. From these data, the molecular structures are described.
- Sponsoring Organization:
- USDOE
- OSTI ID:
- 420962
- Journal Information:
- Inorganic Chemistry, Vol. 33, Issue 15; Other Information: PBD: 20 Jul 1994
- Country of Publication:
- United States
- Language:
- English
Similar Records
Water-Free Rare Earth-Prussian Blue Type Analogues: Synthesis, Structure, Computational Analysis, and Magnetic Data of {Ln[superscript III](DMF)[subscript 6]Fe[superscript III](CN)[subcsript 6]}[subscript infinity] (Ln = Rare Earths Excluding Pm)
Syntheses, structure and rare earth metal photoluminescence of new and known isostructural A{sub 2}Mo{sub 4}Sb{sub 2}O{sub 18} (A=Ce, Pr, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu) compounds
Organometallic compounds of the lanthanides. 42/sup 1/ bis(dimethyloxyethane)lithium bis(cyclopentadienyl)bis(trimethylsilyl)lanthanide complexes
Journal Article
·
Wed Nov 04 00:00:00 EST 2009
· Inorg. Chem.
·
OSTI ID:420962
+6 more
Syntheses, structure and rare earth metal photoluminescence of new and known isostructural A{sub 2}Mo{sub 4}Sb{sub 2}O{sub 18} (A=Ce, Pr, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu) compounds
Journal Article
·
Fri Apr 15 00:00:00 EDT 2011
· Journal of Solid State Chemistry
·
OSTI ID:420962
Organometallic compounds of the lanthanides. 42/sup 1/ bis(dimethyloxyethane)lithium bis(cyclopentadienyl)bis(trimethylsilyl)lanthanide complexes
Journal Article
·
Thu Sep 01 00:00:00 EDT 1988
· Organometallics; (United States)
·
OSTI ID:420962
+1 more