Lanthanide complexes of bulky siloxide ligands incorporating pendant amine donors: Synthesis and structural characterization of a volatile tris(siloxide) complex of yttrium(III) and a novel zwitterionic tetrakis(siloxide) of ytterbium(III)
- Univ. of Victoria, British Columbia (Canada)
The authors describe the synthesis of the silanol ligands, HOSi(t-Bu){sub 3{minus}n}[(CH{sub 2})NME{sub 3}]{sub n} (3, n = 2; 4, n = 1). These ligands react with Ln[N(SiMe{sub 3}){sub 2}]{sub 3} yielding the complexes Ln(OSi(t-Bu){sub 3{minus}n}[(CH{sub 2}){sub 3}NMe{sub 2}]{sub n}){sub 3} (5, Ln = Y, n = 2; 6, Ln = y, n = 1; 7, Ln = Ce, n = 1). X-ray diffraction of single crystals of 6 was used for structural characterization. 6 reacts with Ln[N(SiMe{sub 3}){sub 2}]{sub 3} to give Ln[OSi-(t-Bu){sub 2}(CH{sub 2}){sub 3}NMe{sub 2}]{sub 3}[OSi(t-Bu){sub 2}(CH{sub 2}){sub 3}NMe{sub 2}]{sub 3}[OSi(t-Bu){sub 2}(CH{sub 2}){sub 3}NMe{sub 2}H] (8, Ln = Y; 9, Ln = Yb). X-ray diffraction of single crystals of 9 was used for structural characterization.
- Sponsoring Organization:
- USDOE
- OSTI ID:
- 420954
- Journal Information:
- Inorganic Chemistry, Vol. 33, Issue 16; Other Information: PBD: 3 Aug 1994
- Country of Publication:
- United States
- Language:
- English
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