Electrochemical spectroelectrochemical investigations of [(TpTP)M{sup v}L{sub 2}]{sup +}Cl{sup {minus}} where TpTP is the dianion of tetra-p-tolylporphyrin, M = P or Sb, and L = Cl{sup {minus}} or OCH{sub 3}{sup {minus}}
- Univ. of Houston, TX (United States); and others
Electrochemical studies of [(TpTP)M{sup V}(L){sub 2}]{sup +}Cl{sup -} (M = P or Sb, L = OCH{sub 3}{sup -}, and TpTP is the dianion of tetra-p-tolylporphyrin). Voltammetry, EPR, and UV-Visible studies were applied to interpret the electrochemical reactions. It is found that these compounds undergo internal charge transfer from the {pi} anion radical to the Sb(V) or P(V) center.
- Sponsoring Organization:
- USDOE
- OSTI ID:
- 420946
- Journal Information:
- Inorganic Chemistry, Journal Name: Inorganic Chemistry Journal Issue: 20 Vol. 33; ISSN 0020-1669; ISSN INOCAJ
- Country of Publication:
- United States
- Language:
- English
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