Quantifying the diffusive mass transfer of nonreactive solutes in columns of fractured saprolite using flow interruption

Journal Article · Sun Sep 01 04:00:00 EDT 1996 · Soil Science Society of America Journal

DOI:https://doi.org/10.2136/sssaj1996.03615995006000050012x· OSTI ID:420853

Reedy, O C; Jardine, P M ^[1]; Wilson, G V ^[2]; Selim, H M ^[3]

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1. Oak Ridge National Lab., TN (United States)
2. Univ. of Tennessee, Knoxville, TN (United States)
3. Louisiana State Univ., Baton Rouge, LA (United States)

Subsurface transport processes of low-level radioactive contaminants at hazardous waste sites are complex due to a nonuniform distribution of pore regions in heterogeneous media. During transport, contaminant mass is continuously transferred between the various pore regions via hydraulic and concentration gradients. Our objective was to quantify the diffusive mass transfer of a nonreactive solute between the matrix porosity and preferential flow paths in fractured subsurface media. A large, undisturbed soil column (41 cm long by 17 cm diameter) of weathered, fractured shale was acquired from a proposed waste site on the Oak Ridge Reservation in eastern Tennessee. We injected a nonreactive a nonreactive tracer, Br{sup -}, under saturated conditions, interrupting tracer flow for a designated time, and then reinitiating flow. Experiments considered tracer injection and displacement, variations in duration of flow interruption, and variations in flux. Transport of Br{sup -} through the undisturbed medium was characterized by asymmetric breakthrough curves (BTC), indicative of preferential flow coupled with movement into the matrix. Interrupting flow resulted in decreased and increased Br{sup -} concentrations during tracer infusion and displacement, respectively, when flow was reinitiated. More pronounced concentration perturbations were observed at high fluxes and long interrupt durations. These perturbations were driven by solute concentration gradients established between pore regions as a result of preferential flow. 39 refs., 6 figs., 2 tabs.

• Sponsoring Organization: USDOE
• DOE Contract Number: AC05-96OR22464
• OSTI ID: 420853
• Journal Information: Soil Science Society of America Journal, Journal Name: Soil Science Society of America Journal Journal Issue: 5 Vol. 60; ISSN 0361-5995; ISSN SSSJD4
• Country of Publication: United States
• Language: English

Related Subjects

40 CHEMISTRY
42 ENGINEERING
54 ENVIRONMENTAL SCIENCES
58 GEOSCIENCES
BROMINE IONS
DIFFUSION
FLUID FLOW
MASS TRANSFER
POROUS MATERIALS
RADIOACTIVE WASTES
SOILS
TRACER TECHNIQUES