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FLUID-BED CONVERSION OF URANIUM TETRAFLUORIDE TO URANIUM HEXAFLUORIDE

Technical Report ·
DOI:https://doi.org/10.2172/4207375· OSTI ID:4207375

Experiments conducted in a 2 1/2-inch diameter reactor have demonstrated that the continuous fluorination of uranium tetrafluoride to hexafluoride with elemental fluorine in a fluidized bed is possible. Practicable fluorine efficiencies and conversion rates were attained with good temperature control in experiments with refined uranium tetrafluoride. Runs made with crude uranium tetrafluoride, derived from the reduction and hydrofluorination of ore concentrates produced by the acid-leach process, indicated that these also can be processed at satisfactory ratss and efficiencies. Uranium tetrafluoride derived from carbonate-leached ore concentrate gave a lower production rate and was more difficult to process because of sintering tendencies. (auth)

Research Organization:
Argonne National Lab., Lemont, Ill.
DOE Contract Number:
W-31109-ENG-38
NSA Number:
NSA-14-000082
OSTI ID:
4207375
Report Number(s):
ANL-6054
Country of Publication:
United States
Language:
English

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