Chlorinated organic compounds evolved during the combustion of blends of refuse-derived fuels and coals
- Western Kentucky Univ., Bowling Green, KY (United States)
The objective of this study was to examine the possible formation of chlorinated organic compounds during the combustion of blends of refuse derived fuels (RDF) and coal under conditions similar to those of an atmospheric fluidized bed combustion (AFBC) system. A series of experiments were conducted using a TGA interfaced to FTIR and MS systems. Additional experiments using a tube furnace preheated to AFBC operating temperatures were also conducted. The combustion products were cryogenically trapped and analyzed with a GUMS system. The chlorination of phenols and the condensation reactions of chlorophenols were investigated in this study. A possible mechanism for the formation of chlorinated organic; compounds such as dibenzodioxins and dibenzofurans, by chlorination and condensation reactions involving phenols, was proposed.
- DOE Contract Number:
- FG22-94PC94211
- OSTI ID:
- 420566
- Report Number(s):
- CONF-960807--
- Journal Information:
- Preprints of Papers, American Chemical Society, Division of Fuel Chemistry, Journal Name: Preprints of Papers, American Chemical Society, Division of Fuel Chemistry Journal Issue: 3 Vol. 41; ISSN 0569-3772; ISSN ACFPAI
- Country of Publication:
- United States
- Language:
- English
Similar Records
Co-firing high sulfur coal with refuse derived fuels. Technical progress report No. 5, [October--December 1995]
Gaseous HC1 and chlorinated organic compound emissions from refuse-fired waste-to-energy systems. Final report