KINETIC AND EQUILIBRIUM SECONDARY ISOTOPE EFFECTS IN CARBONYL REACTIONS
Journal Article
·
· Chem. & Ind. (London)
OSTI ID:4197908
The methyl hemiacetal dissociation constants were determined for cyclopentanone and cyclopentanone-2, 2. 5. 5-d/sub 4/ in dioxane at 25 deg C over the following range of concentrations: acetone, 0.04 to 0.004 M; methanol, 0.70 to 0.50 M; and hydrogen chloride, 0.005 to 0.100 M. The results are interpreted relative to secondary isotope effects in terms of hyperconjugation. (C.J.G.)
- Research Organization:
- Illinois Inst. of Tech., Chicago
- NSA Number:
- NSA-14-007330
- OSTI ID:
- 4197908
- Journal Information:
- Chem. & Ind. (London), Journal Name: Chem. & Ind. (London) Vol. Vol: No. 43
- Country of Publication:
- Country unknown/Code not available
- Language:
- English
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