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U.S. Department of Energy
Office of Scientific and Technical Information

PROGRESS REPORT ON THE FLUOROX PROCESS FOR APRIL 30, 1957-JANUARY 14, 1958

Technical Report ·
DOI:https://doi.org/10.2172/4194358· OSTI ID:4194358
Progress in the Fluorox program is reported. The chemical reaction of primary interest in the Fluorox program is the oxidation of UF/sub 4/ with O/sub 2/, 2UF/sub 4/ + O/sub 2/ = UO/sub 2/F/sub 2/ + UF/sub 6/; however, to study this process at higher temperatures, the thermal decomposition of UO/sub 2/F/sub 2/, 3UO/sub 2/F/sub 2/ = 2/3 U/sub 3 /O/sub 8/ + UF/sub 6/ + 1/3 O/sub 2/, is being investigated by thermogravimetric methods in the temperature range 750 to 900 deg C. A fluidized bed reactor and a flame reactor have been used successfully to perform the continuous oxidation of UF/sub 4/ with O/sub 2/. The 3-in. fluidized bed reactor was operated up to 825 deg C on both a continuous and batch basis while the flame reactor was used to continuously react finely divided UF/sub 4/ with O/sub 2/ in a CO-O/sub 2/ flame at temperatures greater than 1200 deg C. (auth)
Research Organization:
Oak Ridge National Lab., Tenn.
NSA Number:
NSA-14-009541
OSTI ID:
4194358
Report Number(s):
CF-58-9-66
Country of Publication:
United States
Language:
English