POLAROGRAPHIC DETERMINATION OF FORMATION CONSTANTS OF COMPLEX IONS IN FUSED LiNO$sub 3$-KNO$sub 3$
Journal Article
·
· Journal of the American Chemical Society (U.S.)
A polarographic study of the chloro-complexes of Pb(II), Cd(II), and Ni(II) was made with the dropping mercury electrode in a fused LiNO)--KNO/sub 3/ mixture at 180 deg C. Respectively, 3, 4, and 2 chloro-complexes were found for these ions yielding these formation constants: Pb(II), K/sub 1/ = 42, K/sub 2/ = 3; Cd(II), K/sub 1/ = 200, K/sub 2/ = 15, K/sub 3/ = 40, K/sub 4/ = 5; Ni(II), K/ sub 1/ = 26, K/sub 2/ = 2, K/sub 3/ = 10. The results are compared with other available data. (auth)
- Research Organization:
- Rensselaer Polytechnic Inst., Troy, N.Y.
- Sponsoring Organization:
- USDOE
- NSA Number:
- NSA-14-012554
- OSTI ID:
- 4194137
- Journal Information:
- Journal of the American Chemical Society (U.S.), Journal Name: Journal of the American Chemical Society (U.S.) Vol. Vol: 82; ISSN JACSA
- Country of Publication:
- Country unknown/Code not available
- Language:
- English
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