NUCLEAR MAGNETIC RESONANCE IN LITHIUM CHLORIDE SOLUTIONS

Journal Article · Sun Sep 01 04:00:00 EDT 1963 · Transactions of the Faraday Society (England) Superseded by J. Chem. Soc., Faraday Trans., I and II

DOI:https://doi.org/10.1039/tf9635901972· OSTI ID:4170065

Craig, R A; Richards, R E

Differences in Li/sup 7/ spin-lattice relaxation rate for lithium chloride solutions in water, methanol, and formic acid are due mainly to viscosity effects. With dimethyl formamide as solvent, however, there are increases in relaxation rate beyond those attributable to viscosity changes, suggesting strong specific ion-solvent interactions. Measurements at different concentrations in aqueous solutions indicate that there is no significant ionic contribution to Li/sup 7/ relaxation. The results and also the changes observed in chemical shift of solvent protons in such systems are discussed in terms of ion solvation. (auth)

• Research Organization: Lincoln Coll., Oxford
• NSA Number: NSA-18-000242
• OSTI ID: 4170065
• Journal Information: Transactions of the Faraday Society (England) Superseded by J. Chem. Soc., Faraday Trans., I and II, Journal Name: Transactions of the Faraday Society (England) Superseded by J. Chem. Soc., Faraday Trans., I and II Vol. Vol: 59; ISSN TFSOA
• Country of Publication: Country unknown/Code not available
• Language: English

Related Subjects

ACTIVATION
AMIDES
ATOMIC MODELS
ATOMS
CHEMICAL REACTIONS
CHEMISTRY
COLLISIONS
DEFORMATION
ELECTRONICS
ENERGY
ENERGY LEVELS
EXCITATION
FORMIC ACID
FREE RADICALS
GASES
LATTICES
LIQUIDS
LITHIUM 7
LITHIUM CHLORIDES
METHANOL
METHYL RADICALS
MOLECULES
NUCLEAR MAGNETIC RESONANCE
NUCLEAR REACTIONS
PRECIPITATION
QUANTITY RATIO
RADIATION CHEMISTRY
RADIOISOTOPES
REACTION KINETICS
RELAXATION
SLOWDOWN
SOLIDS
SOLUTIONS
SPECTRAL SHIFT
SPIN
THERMODYNAMICS
VIBRATIONS
VISCOSITY
WATER