Reactions of sigma-bonded organochromium(III)complexes
- Iowa State Univ., Ames, IA (United States)
Three projects were carried out, each dealing with the kinetics and mechanism of reactions of sigma-bonded organochromium(III) complexes of the form (H2O)5CrR2+. Part I describes the kinetics of the reaction of dichloromethylchromium(III) ion with chromium(II) ion in aqueous acid. Part II deals with the radioexchange of 4-pyridinomethylchromium(III) ion with 51Cr2+ and the kinetics of formation of the organochromium species at 55° in 1 M H+. Part III deals with the reactions of Hg2+ and CH3Hg+ with a series of (H2O)5CrR2+ complexes, in which R is an aliphatic alkyl group, a haloalkyl group, or an aralkyl group. (LK)
- Research Organization:
- Ames Lab., Ames, IA (United States)
- Sponsoring Organization:
- US Energy Research and Development Administration (ERDA)
- DOE Contract Number:
- W-7405-ENG-82
- NSA Number:
- NSA-33-011513
- OSTI ID:
- 4153863
- Report Number(s):
- IS-T--704
- Country of Publication:
- United States
- Language:
- English
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