CHLORINE EXCHANGE BETWEEN ANTIMONY TRICHLORIDE AND TRIMETHYLCHLOROSILANE IN BENZENE AND HEXANE. PART II. KINETICS AND MECHANISM OF EXCHANGE

Journal Article · Mon Feb 01 04:00:00 EST 1960 · Journal of the Chemical Society (England) Divided into J. Chem. Soc. A, J. Chem. Soc. B, etc.

DOI:https://doi.org/10.1039/jr9600000708· OSTI ID:4149819

Reid, A F; Mills, R

Isotopic halogen exchange occurs between trimethylchlorosilane and, severally, hydrogen chloride and the chlorides of aluminum, antimony, and magnesium, and between the corresponding bromine compounds. The kinetics of the exchange between antimony trichloride and trimethylchlorosilane in hexane were initially of first order with respect to each reactant, and probably so in benzene also. The kinetics are complicated in hexane by formation of a species allowing more rapid exchange with increased time of contact of the reactants, and further complicated in benzene by the interaction uf the solvent with antimony trichloride. (auth)

• Research Organization: Australian National Univ., Canberra
• NSA Number: NSA-14-011559
• OSTI ID: 4149819
• Journal Information: Journal of the Chemical Society (England) Divided into J. Chem. Soc. A, J. Chem. Soc. B, etc., Journal Name: Journal of the Chemical Society (England) Divided into J. Chem. Soc. A, J. Chem. Soc. B, etc.; ISSN JCSOA
• Country of Publication: Country unknown/Code not available
• Language: English

Related Subjects

ALUMINUM CHLORIDES
ANTIMONY CHLORIDES
BENZENE
BROMIDES
CHEMISTRY
CHLORINE
CHLORINE COMPOUNDS
HALOGENS
HEXANE
INTERACTIONS
ISOTOPIC EXCHANGE
MAGNESIUM CHLORIDES
METHYL RADICALS
REACTION KINETICS
SILANES