KINETICS OF THE DEHYDROGENATION AND DEHYDRATION OF ISOPROPYL ALCOHOL AND THE DEHYDROGENATION OF TETRALIN ON LANTHANUM OXIDE

Journal Article · Tue Oct 01 00:00:00 EDT 1963 · Zhurnal Fizicheskoi Khimii (U.S.S.R.) For English translation see Russ. J. Phys. Chem. (Engl. Transl.)

OSTI ID:4148100

Tolstopyatova, A A; Balandin, A A; Yu, C

All the relative adsorption coefficients of the dehydrogenation and dehydration products of isopropyl alcohol and dehydrogenation products of tetralin are temperaturedependent. The inhibiting action of the products, propylene, water, and acetone in the isopropyl alcohol reaction and hydrogen in the tetralin reaction diminishes as the temperature is raised. Acetone and water possess a relatively high inhibiting effect. The bond energies of C, H, and 0 with La/sub 2/O/sub 3/ were determined by means of the kinetic method from the activation energies. It was found that Q/sub C-Cat/ < Q/sub H-Cat/ < Q/sub O-Cat/ . (auth)

• Research Organization: Inst. of Organic Chemistry, Academy of Sciences, USSR
• NSA Number: NSA-18-001719
• OSTI ID: 4148100
• Journal Information: Zhurnal Fizicheskoi Khimii (U.S.S.R.) For English translation see Russ. J. Phys. Chem. (Engl. Transl.), Vol. Vol: 37; Other Information: Orig. Receipt Date: 31-DEC-64
• Country of Publication: Country unknown/Code not available
• Language: Russian

Related Subjects

CHEMISTRY
ACETONE
ACTIVATION ENERGY
ADSORPTION
BINDING ENERGY
BIOCHEMISTRY
CARBON
CHEMICAL REACTIONS
CORROSION PROTECTION
DEHYDRATION
DEHYDROGENATION
EVAPORATION
EXCITATION
HYDROGEN
HYDROGENATION
INHIBITION
ISOMERS
LANTHANUM OXIDES
LATTICES
NAPHTHALENE
OXYGEN
PROPANOL
PROPYLENE
QUANTITATIVE ANALYSIS
REACTION KINETICS
STERILIZATION
TEMPERATURE
TETRALIN
WATER