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QUANTUM MECHANICAL LAW OF CORRESPONDING STATES FOR VAN DER WAALS SOLIDS AT 0 K

Journal Article · · Physical Review (U.S.) Superseded in part by Phys. Rev. A, Phys. Rev. B: Solid State, Phys. Rev. C, and Phys. Rev. D
A quantum mechanical variational treatment based on a simple Heitler- London wave funition is used to describe the various properties of Van der Waals solids at 0 deg KH. The effects of nuclear motion on the cohesive energy, volume, compressibility, sound velocity, etc., are discussed. These effects can be expressed in the form of a power series in h, of which we show the first term, linear in h, explicitly. The results are in good agreement with the available experimental data for all solidified inert gases, except for helium to which the present method is not applicable. (auth)
Research Organization:
Ames Lab., Ames, Iowa
NSA Number:
NSA-15-003269
OSTI ID:
4145022
Report Number(s):
IS-142; 0031-899X
Journal Information:
Physical Review (U.S.) Superseded in part by Phys. Rev. A, Phys. Rev. B: Solid State, Phys. Rev. C, and Phys. Rev. D, Journal Name: Physical Review (U.S.) Superseded in part by Phys. Rev. A, Phys. Rev. B: Solid State, Phys. Rev. C, and Phys. Rev. D Vol. Vol: 120; ISSN PHRVA
Country of Publication:
Country unknown/Code not available
Language:
English

References (9)

Van der waals forces journal January 1939
Theory of Solid Ne, A, Kr, and Xe at 0°K journal December 1958
Quantum theory of condensed permanent gases II the solid state and the melting line journal April 1948
Potential energy matrix elements between non-overlapping wave functions journal March 1959
Atomic Distribution in Liquid and Solid Neon and Solid Argon by Neutron Diffraction journal September 1958
The Van Der Waals Forces in Gases journal March 1931
Compression of solidified gases to 20,000 kg/cm2 at low temperature journal November 1956
CXX. Measurement of the elasticity of solid argon with an ultrasonic interferometer journal October 1955
Grüneisen parameters for the equation of state of solids journal April 1957

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