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U.S. Department of Energy
Office of Scientific and Technical Information

Plasma sprayed coatings as surface treatments of aluminum adherends

Conference ·
OSTI ID:412051
; ; ;  [1]
  1. Lockheed Martin, Baltimore, MD (United States); and others

Plasma sprayed coatings have been evaluated as surface treatments for aluminum substrates being prepared for adhesive bonding. Blends of an aluminum-silicon alloy and polyester give the best performance. To establish durability performance, wedge tests were done using four common epoxy adhesives without primers. In all cases, the 60%Al-Si/40%polyester coating gave results superior to those of FPL-etched specimens and, in some cases, performance equivalent to PAA specimens. This roughness provides excellent opportunity for mechanical interlocking or physical bonding and allows a complex interphase to be formed as the adhesive penetrates into the coating. Crack growth measurements and subsequent failure analysis using x-ray photoelectron spectroscopy (XPS) indicate that crack propagation occurs within this complex interphase. The results also show that the aluminum and polyester components are synergistic and blends of the two give better performance than either component by itself The aluminum gives strength to the coating while the polyester provides toughness and improves moisture resistance.

OSTI ID:
412051
Report Number(s):
CONF-960310--; CNN: Contract F33615-93-C-5324
Country of Publication:
United States
Language:
English