HIGH-RESOLUTION N.M.R. SPECTRA IN ELECTRIC FIELDS
Journal Article
·
· Transactions of the Faraday Society (England) Superseded by J. Chem. Soc., Faraday Trans., I and II
A general method of calculating high-resolution nuclear magnetic resonance spectra of polar fluids in electric fields is described. The partial orientation of the molecular electric dipole moments in a strong electric field modifies the averaging of the tensors representing nuclear magnetic shielding and spin-spin coupling. An effective Hamiltonian for polarized fluids is deduced and used to predict spectral changes in certain standard types of n.m.r. spectra involving spin-1/2 nuclei. Equivalent nuclei are found to produce splittings propotrional tot he inverse cube of their separation. (auth)
- Research Organization:
- Oxford Univ.
- NSA Number:
- NSA-18-006828
- OSTI ID:
- 4120106
- Journal Information:
- Transactions of the Faraday Society (England) Superseded by J. Chem. Soc., Faraday Trans., I and II, Journal Name: Transactions of the Faraday Society (England) Superseded by J. Chem. Soc., Faraday Trans., I and II Vol. Vol: 59; ISSN TFSOA
- Country of Publication:
- Country unknown/Code not available
- Language:
- English
Similar Records
Communication: Permanent dipoles contribute to electric polarization in chiral NMR spectra
Nuclear relaxation in an electric field enables the determination of isotropic magnetic shielding
ELECTRON-NUCLEAR DOUBLE RESONANCE SPECTRUM OF AN F-CENTER ELECTRON IN ALKALI HALIDES (WITH NaCl STRUCTURE)
Journal Article
·
Mon Jan 06 23:00:00 EST 2014
· Journal of Chemical Physics
·
OSTI ID:22253646
Nuclear relaxation in an electric field enables the determination of isotropic magnetic shielding
Journal Article
·
Sun Aug 14 00:00:00 EDT 2016
· Journal of Chemical Physics
·
OSTI ID:22678979
ELECTRON-NUCLEAR DOUBLE RESONANCE SPECTRUM OF AN F-CENTER ELECTRON IN ALKALI HALIDES (WITH NaCl STRUCTURE)
Journal Article
·
Fri Jun 01 00:00:00 EDT 1962
· Physical Review (U.S.) Superseded in part by Phys. Rev. A, Phys. Rev. B: Solid State, Phys. Rev. C, and Phys. Rev. D
·
OSTI ID:4820175