IRRADIATED CHEMICAL REACTIONS
Patent
·
OSTI ID:4119794
A process for preparing fluoride compounds without the use of inorganic and organic catalysts is described. At least one organic fluoride compound is reacted with at least one nonfluorinated olefinically or acetylenically unsaturated organic compound with a molecular weight below 1000 at a pressure less than 1000 psig in the presence of gamma radiation. The solid reaction product is recovered. Ten examples are given. It was provided that when the organic fluoride connpound is trifluorochloroethylene the nonfluorinated compound is not a monomer having the general formula H/sub 2/C = CR/sub 1/R/sub 2/where R/ sub 1/ represents H or CH/sub 3/ and R/sub 2/ represents CR/sub 3/, Cl, OC = OCH/ sub 3/, COOCH/sub 3/, or COOC/sub 2/H/sub 5/, and that when the unsaturated organic compound is ethylene the fluoride compound is not a fluorinated methane containing one or more chlorine, bromine, or iodine atoms. (M.C.G.)
- Research Organization:
- Originating Research Org. not identified
- NSA Number:
- NSA-18-006878
- OSTI ID:
- 4119794
- Report Number(s):
- GB 946050
- Country of Publication:
- United Kingdom
- Language:
- English
Similar Records
Coating compositions hardenable by ionization beams
Method for recovering petroleum using oligomeric surfactants
Catalytic hydrogenation of aromatic hydrocarbons. Stereochemical definition of the catalytic cycle for eta/sup 3/-C/sub 3/H/sub 5/Co(P(OCH/sub 3/)/sub 3/)/sub 3/
Patent
·
Mon Apr 05 23:00:00 EST 1976
·
OSTI ID:7224663
Method for recovering petroleum using oligomeric surfactants
Patent
·
Tue Apr 11 00:00:00 EDT 1989
·
OSTI ID:5716872
Catalytic hydrogenation of aromatic hydrocarbons. Stereochemical definition of the catalytic cycle for eta/sup 3/-C/sub 3/H/sub 5/Co(P(OCH/sub 3/)/sub 3/)/sub 3/
Journal Article
·
Tue Feb 10 23:00:00 EST 1981
· J. Am. Chem. Soc.; (United States)
·
OSTI ID:6644373
Related Subjects
ACETIC ACID
ACETYLENES
ALKANES
CATALYSIS
CHEMICAL REACTIONS
CHEMISTRY
COMPOUNDS
CONFIGURATION
ETHERS
ETHYL RADICALS
ETHYLENE
FLUORIDES
GAMMA RADIATION
KETONES
METHANE
METHYL RADICALS
MOLECULES
OPERATION
ORGANIC ACIDS
ORGANIC BROMINE COMPOUNDS
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC FLUORINE COMPOUNDS
ORGANIC IODINE COMPOUNDS
PATENT
PERFORMANCE
PREPARATION
PRESSURE
PROPYL RADICALS
RADIATION CHEMISTRY
RECOVERY
SOLIDS
WEIGHT
ACETYLENES
ALKANES
CATALYSIS
CHEMICAL REACTIONS
CHEMISTRY
COMPOUNDS
CONFIGURATION
ETHERS
ETHYL RADICALS
ETHYLENE
FLUORIDES
GAMMA RADIATION
KETONES
METHANE
METHYL RADICALS
MOLECULES
OPERATION
ORGANIC ACIDS
ORGANIC BROMINE COMPOUNDS
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC FLUORINE COMPOUNDS
ORGANIC IODINE COMPOUNDS
PATENT
PERFORMANCE
PREPARATION
PRESSURE
PROPYL RADICALS
RADIATION CHEMISTRY
RECOVERY
SOLIDS
WEIGHT