Collision-induced emission from O($sup 1$S) by He, Ar, N$sub 2$, H$sub 2$, Kr, and Xe

Journal Article · Sat Nov 15 04:00:00 EST 1975 · J. Chem. Phys., v. 63, no. 10, pp. 4546-4550

OSTI ID:4116378

Black, G; Sharpless, R L; Slanger, T G

Collision-induced emission from O($sup 1$S) has been studied for collisions with He, Ar, N$sub 2$, H$sub 2$, Kr, and Xe. The O($sup 1$S) was made by CO$sub 2$ photodissociation at 1120 A and N$sub 2$O photodissociation at 1290 A. For all but Xe the emitted intensity (including both atomic line and associated molecular bands) increased linearly with the added gas pressure. This was not true at low pressures of Xe--the observed behavior in this case was used to deduce the rates for formation and collisional dissociation of XeO. (auth)

• Research Organization: Stanford Research Inst., Menlo Park, CA
• NSA Number: NSA-33-013022
• OSTI ID: 4116378
• Journal Information: J. Chem. Phys., v. 63, no. 10, pp. 4546-4550, Journal Name: J. Chem. Phys., v. 63, no. 10, pp. 4546-4550; ISSN JCPSA
• Country of Publication: United States
• Language: English

Related Subjects

*ARGON-- ATOM-ATOM COLLISIONS
*HELIUM-- ATOM-ATOM COLLISIONS
*HYDROGEN-- ATOM-MOLECULE COLLISIONS
*KRYPTON-- ATOM-ATOM COLLISIONS
*NITROGEN-- ATOM-MOLECULE COLLISIONS
*OXYGEN-- ATOM-ATOM COLLISIONS
*XENON-- ATOM-ATOM COLLISIONS
640304* --Physics Research--Atomic
Molecular & Chemical Physics--Collision Phenomena
EMISSION SPECTRA
N60400* --Physics (Atomic & Molecular)--Collision Phenomena
RARE GAS COMPOUNDS