Halogen atom reactions activated by nuclear transformations. Progress report, February 15, 1975--February 14, 1976
High energy reactions of halogen atoms or ions, activated by nuclear transformations, are being studied in gaseous, high pressure, and condensed phase saturated and unsaturated hydrocarbons, halomethanes, and other organic systems. Experimental and theoretical data are presented in the following areas: systematics of iodine hot atom reactions in halomethanes, reactions and systematics of iodine reactions with pentene and butene isomers, radiative neutron capture activated reactions of iodine with acetylene, gas to liquid to solid transition in hot atom chemistry, kinetic theory applications of hot atom reactions and the mathematical development of caging reactions, solvent dependence of the stereochemistry of the $sup 38$Cl for Cl substitution following $sup 37$Cl(n,$gamma$$)$$sup 38$Cl in liquid meso and dl-(CHFCl)$sub 2$. A technique was also developed for the radioassay of Al in urine specimens. (JSR)
- Research Organization:
- Nebraska Univ., Lincoln (USA). Dept. of Chemistry
- NSA Number:
- NSA-33-016681
- OSTI ID:
- 4107955
- Report Number(s):
- COO--1617-45
- Country of Publication:
- United States
- Language:
- English
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Thu Apr 15 00:00:00 EDT 1993
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Related Subjects
*ACETYLENE-- HOT ATOM CHEMISTRY
*ALUMINIUM-- RADIOASSAY
*BUTENES-- HOT ATOM CHEMISTRY
*CHLORINE 38-- HOT ATOM CHEMISTRY
*HALOGENATED ALIPHATIC HYDROCARBONS-- HOT ATOM CHEMISTRY
*HOT ATOM CHEMISTRY-- PHASE TRANSFORMATIONS
*IODINE 128-- HOT ATOM CHEMISTRY
*IODINE 130-- HOT ATOM CHEMISTRY
*IODINE 131-- HOT ATOM CHEMISTRY
*PENTENES-- HOT ATOM CHEMISTRY
*URINE-- CHEMICAL ANALYSIS
400701* --Chemistry--Radiochemistry & Nuclear Chemistry--Hot- Atom Chemistry
CHEMICAL REACTION KINETICS
N40130 --Chemistry--Analytical & Separations Chemistry--Radiometric & Radiochemical Procedures
N40410* --Chemistry--Radiochemistry & Nuclear Chemistry--Hot Atom Chemistry
QUALITATIVE CHEMICAL ANALYSIS
RESEARCH PROGRAMS
*ALUMINIUM-- RADIOASSAY
*BUTENES-- HOT ATOM CHEMISTRY
*CHLORINE 38-- HOT ATOM CHEMISTRY
*HALOGENATED ALIPHATIC HYDROCARBONS-- HOT ATOM CHEMISTRY
*HOT ATOM CHEMISTRY-- PHASE TRANSFORMATIONS
*IODINE 128-- HOT ATOM CHEMISTRY
*IODINE 130-- HOT ATOM CHEMISTRY
*IODINE 131-- HOT ATOM CHEMISTRY
*PENTENES-- HOT ATOM CHEMISTRY
*URINE-- CHEMICAL ANALYSIS
400701* --Chemistry--Radiochemistry & Nuclear Chemistry--Hot- Atom Chemistry
CHEMICAL REACTION KINETICS
N40130 --Chemistry--Analytical & Separations Chemistry--Radiometric & Radiochemical Procedures
N40410* --Chemistry--Radiochemistry & Nuclear Chemistry--Hot Atom Chemistry
QUALITATIVE CHEMICAL ANALYSIS
RESEARCH PROGRAMS