OXIDATION BEHAVIOR OF BINARY NIOBIUM ALLOYS
A screening study on the oxidation resistance of 33 binary alloy systems of niobium is reported. Alloys containing up to 25 nominal at. % of the alloying element were prepared by powder-metallurgy techniques and oxidized in air for 4 hr at lOOO deg C and 2 hr at 1200 deg C. The alloy sys tems showing the best oxidation resistance were Nb-- Cr, Nb--Ti, Nb--Al, Nb--V, and, to a lesser extent, Nb-- Fe, Nb-- Co, Nb-- Cu, and Nb--Ir. The chief factor contributing to this protection appears to be the ion size of the alloy addition. It should be slightly smaller than that of the Nb/sup 5+/ ion in order to dissolve in the Nb/ sub 2/O/sub 5/ oxide and lower the compressive stresses that crack the scale. (auth)
- Research Organization:
- National Aeronautics and Space Administration. Lewis Research Center, Cleveland
- NSA Number:
- NSA-15-006380
- OSTI ID:
- 4107649
- Report Number(s):
- NASA-TN-D-283
- Country of Publication:
- United States
- Language:
- English
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