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U.S. Department of Energy
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OXIDATION BEHAVIOR OF BINARY NIOBIUM ALLOYS

Technical Report ·
OSTI ID:4107649

A screening study on the oxidation resistance of 33 binary alloy systems of niobium is reported. Alloys containing up to 25 nominal at. % of the alloying element were prepared by powder-metallurgy techniques and oxidized in air for 4 hr at lOOO deg C and 2 hr at 1200 deg C. The alloy sys tems showing the best oxidation resistance were Nb-- Cr, Nb--Ti, Nb--Al, Nb--V, and, to a lesser extent, Nb-- Fe, Nb-- Co, Nb-- Cu, and Nb--Ir. The chief factor contributing to this protection appears to be the ion size of the alloy addition. It should be slightly smaller than that of the Nb/sup 5+/ ion in order to dissolve in the Nb/ sub 2/O/sub 5/ oxide and lower the compressive stresses that crack the scale. (auth)

Research Organization:
National Aeronautics and Space Administration. Lewis Research Center, Cleveland
NSA Number:
NSA-15-006380
OSTI ID:
4107649
Report Number(s):
NASA-TN-D-283
Country of Publication:
United States
Language:
English