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THE SEPARATION OF HYDROGEN, DEUTERIUM AND HYDROGEN DEUTERIDE MIXTURES BY GAS CHROMATOGRAPHY

Journal Article · · Journal of Physical Chemistry
DOI:https://doi.org/10.1021/j100819a027· OSTI ID:4098572
The resolution and analysis of the components of hydrogen--deuterium mixtures were accomplished by gas chromatography at 77 ts K. Neon was employed as the carrier gas, and the column was chromia deposited on alumina. Orthohydrogen and parahydrogen did not separate on the chromia--alumina column. The separation factor for hydrogen deuteride and deuterium was much greater than that for hydrogen and hydrogen deuteride. The complete separation of deuterium and hydrogen deuteride was also obtained on a silica gel column with hydrogen as the carrier gas, whereas a charcoal column produced very little separation. (auth)
Research Organization:
Univ. of Tennessee, Knoxville
Sponsoring Organization:
USDOE
NSA Number:
NSA-15-009298
OSTI ID:
4098572
Journal Information:
Journal of Physical Chemistry, Journal Name: Journal of Physical Chemistry Journal Issue: 1 Vol. 65; ISSN 0022-3654
Country of Publication:
Country unknown/Code not available
Language:
English

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