Ultraviolet spectrum of trans-1,3-butadiene

Journal Article · Thu Jan 15 04:00:00 EST 1976 · J. Chem. Phys., v. 64, no. 2, pp. 514-521

DOI:https://doi.org/10.1063/1.432240· OSTI ID:4096939

McDiarmid, R

The ultraviolet absorption spectra of trans-1,3-butadiene, 1,1,4,4-trans- 1,3-butadiene-d$sub 4$, and trans-1,3-butadiene-d$sub 6$ between 2300 and 1350 A have been recorded and analyzed. Four Rydberg series were identified (delta=0.087, 0.21, 0.42, and 0.67). A transition-by-transition comparison of this analysis with those in the literature shows that several of the previously assigned transitions are misidentified. A continuum originating around 1450 A is reported. (AIP)

• Research Organization: Laboratory of Chemical Physics, National Institute of Arthritis, Metabolism and Digestive Diseases, National Institutes of Health, Bethesda, Maryland 20014
• Sponsoring Organization: USDOE
• NSA Number: NSA-33-019700
• OSTI ID: 4096939
• Journal Information: J. Chem. Phys., v. 64, no. 2, pp. 514-521, Journal Name: J. Chem. Phys., v. 64, no. 2, pp. 514-521; ISSN JCPSA
• Country of Publication: United States
• Language: English

Related Subjects

*DEUTERIUM-- ISOTOPE EFFECTS
400302* --Chemistry--Organic Chemistry--Isotope Effects
BUTADIENE
N40220* --Chemistry--Inorganic
Organic
& Physical Chemistry--Isotopic Effects
RYDBERG CORRECTION
ULTRAVIOLET SPECTRA