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RAMAN SPECTRUM AND INFRARED SPECTRUM OF DEUTERATED VINYL CHLORIDES (in French)

Journal Article · · Bull. classe sci., Acad roy. Belg.
OSTI ID:4094806
The Raman vibration spectrum of the molecules CHD = CHCl, CHD = CDCl, and CD/sub 2/ = CDCl in the liquid phase was photographed by means of a prism spectrograph using the Hg 4358 A line as the exciting beam. The infrared spectrum of the molecules CHD = CHCl and CHD = CDCl in the liquid phase was recorded from 400 to 3200 cm/sup -1/ with a prism spectrometer. The diffusion and adsorption rays observed were attributed to the self-vibrations of these molecules. The attributions were controlled by the TellerRedlich rule and the sum rule. Two different preparations of the products permit the separation of the self-vibrations of the "cis" and "trans" forms of the molecules CHD = CHCl and CHD = CDCl. (tr-auth)
Research Organization:
Univ., Louvain
NSA Number:
NSA-15-008801
OSTI ID:
4094806
Journal Information:
Bull. classe sci., Acad roy. Belg., Journal Name: Bull. classe sci., Acad roy. Belg. Vol. Vol: 46
Country of Publication:
Country unknown/Code not available
Language:
French

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